This makes logical sense in theory though I've never experienced this issue. I admit I don't put a lot of miles on my cars and this may be why. I imagine some high flow cats would perform much better since the cells are bigger in comparison to factory cats. I actually play on changing the headers on my Cayman since they make significantly more power with aftermarket headers anyway and I wanted bigger cells. I can't imagine the bigger cells getting clogged like the tiny ones do. Now for the Hellcat, I wasn't planning on changing the factory headers since they're pretty efficient but if they clog, I'll definitely go high flow or no cats at all with a custom tune. The residue on the cats doesn't bother me but I suppose I can see that being a problem for some if it's a proven issue.
High flow cats are not better. They are worse.
The converter cells need to be small and many (in the hundreds) to provide sufficient surface area so the exhaust gases can come in direct contact the cell surfaces which have the catalytic metals which latch on and retain excess oxygen in the exhaust gases. This is provided by an engine controller which slightly varies the air/fuel ratio to intermittently provide a sightly leaner mixture -- which has excess oxygen in the exhaust -- and a slighly richer mixture. The oxygen stored when the mixture is lean and not all used in this phase is then used when the mixture is richer.
With insufficient surface area excess oxygen in the exhaust gas can't be "grabbed" by the catalytic metals and stored. The efficiency of the converter is reduced.
Also with larger cells high flow cats probably have less surface area and which also means there is less catalytic metal. In this case the oxidation process is reduced which means less heat is generated which works to lower the efficiency of the converters. They are intended to work "hot" and the heat is partially provided for by proper operation. The high heat is needed to sustain proper conversion of the bad exhaust gasses into something less bad.
The cells do not get clogged the working surfaces get coated and prevent the direct contact of the exhaust gas -- which includes oxygen -- with the catalytic metals. This is a concern when oils with levels of ZDDP are used. The ZDDP under high temperature conditions such as found in the converters (which can operate at 600C (around 1000F) form a glass like like compound which coats the working converter sufaces.